PUBLICATIONS

50/

Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization

Gao, W.-Y.; Sur, A.; Wang, C.-H.; Lorzing, G. R.;Antonio, A. M.; Ezazi, A. A.; Bhuvanesh, N.; Bloch, E. D.; and Powers, D. C. Pre-print: ChemRxiv, 2020, https://doi.org/10.26434/chemrxiv.11879304.v1

49/

Electrocatalytic C–N Coupling via Anodically Generated Hypervalent Iodine Intermediates

 Maity, A.; Frey, B. L.; Hoskinson, N. D.; Powers, D. C. J. Am. Chem. Soc. 2020, J. Am. Chem. Soc. 2020,  142, 4990−4995.  doi:10.1021/jacs.9b13918. (Pre-print: ChemRxiv, 2019, https://chemrxiv.org/s/f142a8eb0537f4c6213d).

48/

Measuring and Modulating Substrate Confinement during Nitrogen-Atom Transfer in a Ru2-Based Metal-Organic Framework

 Wang, C.-H.; Gao, W.-Y.; Powers, D. C. J. Am. Chem. Soc. 2019, J. Am. Chem. Soc. 2019, 141, 19203−19207. doi: 10.1021/jacs.9b09620.

(Pre-print: ChemRxiv, 2019, DOI:https://doi.org/10.26434/chemrxiv.9784514.v1).

47/

Characterization of a Reactive Rh2 Nitrenoid by Crystalline Matrix Isolation

Das, A.; Chen, Y.-S.; Reibenspies, J. H.; Powers, D. C. J. Am. Chem. Soc. 2019, 141, 16232−16236. doi: 10.1021/jacs.9b09064.

(Pre-print: ChemRxiv, 2019, DOI: https://doi.org/10.26434/chemrxiv.9273395.v1).

46/

The Role of Iodanyl Radicals as Critical Chain Carriers in Aerobic Hypervalent Iodine Chemistry

Hyun, S.-M.; Yuan, M.; Maity, A.; Gutierrez, O.; Powers, D. C. Chem 2019, 5, 2388–2404. doi: 10.1016/j.chempr.2019.06.006.

45/

Iodosylbenzene Coordination Chemistry Relevant to MOF Catalysis

Cardenal, A. D.; Maity, A.; Gao, W.-Y.; Ashirov, R.; Hyun, S.-M.; Powers, D. C. Inorg. Chem. 2019, 58, 10543−10553. doi: 10.1021/acs.inorgchem.9b01191.

44/

Metallopolymerization as a Strategy to Translate Ligand-Modulated Chemoselectivity to Porous Catalysts

Gao, W.-Y.; Ezazi, A. A.; Wang, C.-H.; Moon, J.; Abney, C.; Wright, J.; Powers, D. C. Organometallics 2019, 38, 3436–3443. doi:10.1021/acs.organomet.9b00162. 

(Pre-print: ChemRxiv, 2019, DOI: 10.26434/chemrxiv.7538747.v1).

43/

High-Frequency and -Field EPR (HFEPR) Investigation of a Pseudotetrahedral Cr(IV) Siloxide Complex and Computational Studies of Related Cr(IV)L4 Systems

Bucinsky, L.; Breza, M.; Powers, D. C.; Hwang, S. J.; Kyzystek, J.; Nocera, D. G.; Telser, J. Inorg. Chem. 2019, 58, 4907-4920.

doi: 10.1021/acs.inorgchem.8b03512.

42/

Templating Metastable Pd2 Carboxylate Aggregates

Wang, C.-H.; Gao, W.-Y.; Ma, Q.; Powers, D. C. Chem. Sci. 2019, 10, 1823-1830. doi: 10.1039/C8SC04940H.

41/

Hypervalent Iodine Chemistry as a Platform for Aerobic Oxidation Catalysis

Maity, A.; Powers, D. C. Synlett 2019, 30, 257–262. doi: 10.1055/s-0037-1610338. (Invited Highlight).

40/

 In Operando Analysis of Diffusion in Porous Metal-Organic Framework Catalysts

Gao, W.-Y.; Cardenal, A. D.; Wang, C.-H.; Powers, D. C. Chem. Eur. J. 2019, 25, 3465-3476. doi: 10.1002/chem.201804490.

39/

 Observation of a Photogenerated Rh2 Nitrenoid Intermediate in C-H Amination

Das, A.; Maher, A. G.; Telser, J.; Powers, D. C. J. Am. Chem. Soc. 2018, 140, 10412-10415. doi: 10.1021/jacs.8b05599.

38/

 Oxidation Catalysis via an Aerobically Generated Dess-Martin Periodinane Analogue

Maity, A.; Hyun, S.-M.; Wortman, A. K.; Powers, D. C. Angew. Chem. Int. Ed. 2018, 57, 7205-7209. doi: 10.1002/anie.201804159. (Preprint available: ChemRxiv, 2018, doi: 10.26434/chemrxiv.6149276)

37/

 Probing Substrate Diffusion in Interstitial MOF CHemistry with Kinetic Isotope Effects

Wang, C.-H.; Das, A.; Gao, W.-Y.; Powers, D. C. Angew. Chem. Int. Ed. 2018, 57, 3676-3681. doi: 10.1002/anie.201713244. (Preprint available: ChemRxiv, 2018, doi: 10.26434/chemrxiv.5883142.v1)

36/

Oxidase Catalysis via Aerobically Generated Hypervalent Iodine Intermediates

Maity, A.; Hyun, S.-M.; Powers, D. C. Nat. Chem.  2018, 10, 200-204. doi: 10.1038/nchem.2873. (Preprint available: ChemRxiv, 2017,

doi: 10.26434/chemrxiv.5419270.v1)

35/

Cis-Decalin Oxidation as a Stereochemical Probe of in-MOF versus on-MOF Catalysis

Cardenal, A. D.; Park, H. J.; Chalker, C. J.; Ortiz, K. G.; Powers, D. C. Chem. Commun.  2017, 53, 7377-7380. doi: 10.1039/C7CC02570J.

34/

Direct Characterization of a Reactive Lattice-Confined Ru2 Nitride by Photocrystallography

Das, A.; Reibenspies, J. H.; Chen, Y.-S.; Powers, D. C.  J. Am. Chem. Soc.  2017, 139, 2912-2915. doi: 10.1021/jacs.6b13357.

33/

 Oxidation of Metal–Carbon Bonds

Cardenal, A. D.; Powers, D. C. Chem. Molec. Sci. Chem. Eng. 2016, 55, 1–27. doi: 10.1016/B978-0-12-409547-2.13796-5.

Prior to independent career

32/  Halogen Photoelimination from Sb(V) Dihalide Corroles

Lemon, C. M.; Hwang, S. J.; Maher, A. G. Powers, D. C.; Nocera, D. G. Inorg. Chem. 2018, 57, 5333-5342.

doi: 10.1021/acs.inorgchem.8b00314.

31/ Gold Corroles as Near-IR Phosphors for Oxygen Sensing

Lemon, C. M.; Powers, D. C.; Brother, P. J.; Nocera, D. G.  Inorg. Chem. 201756, 10991–10997.

30/ The Energetics and Mechanism of Cl2 Elimination from Binuclear Pt(III) Complexes

Powers, D. C.; Hwang, S. J.; Anderson, B. L.; Yang, H.; Zheng, S.-L. Chen, Y.-S.; Cook, T. R.; Gabbai, F. P.; Nocera, D. G. Inorg. Chem. 2016, 55, 11815–11820.

29/ Electronic Structure of Copper Corroles

Lemon, C. M.; Huynh, M.; Maher, A. G.; Anderson, B. L.; Bloch, E. D.; Powers, D. C.; Nocera, D. G. Angew. Chem., Int. Ed. 201655,

2176–2180.

28/ Secondary Coordination Sphere Effects in Halogen Photoelimination from Monomeric Ni(III) Complexes 

Hwang, S. J.; Anderson, B. L.; Powers, D. C.; Maher, A. G.; Hadt, R. G.; Nocera, D. G. Organometallics 201534, 4766–4774.

27/ Trap-Free Chlorine Photoelimination from Mononuclear Ni(III) Complexes

Hwang, S. J.; Powers, D. C.; Maher, A. G.; Anderson, B. L.; Hadt, R. G.; Zheng, S.-L.; Chen, Y.-S.; Nocera, D. G. J. Am. Chem. Soc. 2015137, 6472–6475.

26/  Tandem Redox Mediator/Ni(II) Trihalide Complex Photocycle for Hydrogen Evolution from HCl 

Hwang, S. J.; Powers, D. C.; Maher, A. G.; Nocera, D. G. Chem. Sci. 20156, 917–922.

25/ Water Oxidation Catalysis by Co(II) Impurities in Co(III)4O4 Cubanes 

Ullman, A. M.; Liu, Y.; Bediako, D. K.; Huynh, M.; Wang, H.; Anderson, B. L.; Powers, D. C.; Breen, J. J. Abruña, H. D.; Nocera, D. G. J. Am. Chem. Soc2014136, 17681–17688.

24/  Photocrystallographic Observation of Halide-Bridged Intermediates in Halogen Photoeliminations 

Powers, D. C.; Anderson, B. L.; Hwang, S. J.; Powers, T. M.; Pérez, L. M.; Hall, M. B.; Zheng, S.-L.; Chen, Y.-S.; Nocera; D. G. J. Am. Chem. Soc. 2014136, 15346–15355. (Highlighted in: Nature Chem. 20157, 12–13.)

23/ Theoretical Analysis of Cobalt Hangman Porphyrins: Ligand Dearomatization and Mechanistic Implications for Hydrogen Evolution

Solis, B. H.; Maher, A. G.; Honda, T. Powers, D. C.; Nocera, D. G.; Hammes-Schiffer, S. ACS Catal. 20144, 4516–4526.

22/ Halide-Bridged Binuclear HX-Splitting Catalysts 

Powers, D. C.; Hwang, S. J.; Zheng, S.-L.; Nocera, D. G. Inorg. Chem. 201453, 9122–9128.

21/ Oxidation of Carbon–Metal Bonds 

Powers, D. C.; Ritter, T.  Comp. Org. Synth. 2014, Chapter 7.27.

20/ Metal–Metal Bond-Containing Complexes as Catalysts for C–H Functionalization 

Kornecki, K.; Berry, J. F.; Powers, D. C.; Ritter, T. Prog. Inorg. Chem. 201458, 223–300.

19/ Two-Electron Photoreduction of a Ni(II) Halide Enables H2 Evolution from HCl

Powers, D. C.; Anderson, B. L.; Nocera, D. G. J. Am. Chem. Soc. 2013135, 18876–18883.

18/  Halogen Photoelimination from Dirhodium Phosphazane Complexes via Chloride-Bridged Intermediates 

Powers, D. C.; Chambers, M. B.; Teets, T. S.; Elgrishi, N.; Anderson, B. L.; Nocera, D. G. Chem. Sci. 20134, 2880–2885.

17/ A Transition State Analogue for the Oxidation of Binuclear Palladium(II) to Binuclear Palladium(III) Complexes 

Powers, D. C.; Ritter, T.  Organometallics 201332, 2042–2045.

16/ Bimetallic Catalysis with Palladium 

Powers, D. C.; Ritter, T. In Science of Synthesis; Trost, B. M.; Stoltz, B. M., Eds.; Thieme: Stuttgart, 2012; Vol. 1, 1–31.

15/ Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage 

Powers, D. C.; Lee, E.; Ariafard, A.; Sanford, M. S.; Yates, B. F.; Canty, A. J.; Ritter, T. J. Am. Chem. Soc. 2012134, 12002–12009. 

14/ Bimetallic Redox Synergy in Oxidative Palladium Catalysis 

Powers, D. C.; Ritter, T.  Acc. Chem. Res. 2012, 45, 840–850. 

13/ Synthesis and Structure of Solution-Stable One-Dimensional Palladium Wires 

Campbell, M. G.; Powers, D. C.; Raynaud, J.; Graham, M. J.; Xie, P.; Lee, E.; Ritter, T. Nature Chem. 20113, 949–953. 

12/ A Fluoride-Derived Electrophilic Late-Stage Fluorination Reagent for PET Imaging 

Lee, E.; Kamlet, A. S.; Powers, D. C.; Neumann, C. N.; Boursalian, G. B.; Furuya, T.; Choi, D. C.; Hooker, J. M.; Ritter, T. Science 2011334, 639–642. 

11/ Palladium(III) in Synthesis and Catalysis

Powers, D. C.; Ritter, T.  Top. Organomet. Chem. 201135, 129–156.

10/ On the Mechanism of Palladium-Catalyzed Aromatic C–H Oxidation 

Powers, D. C.; Xiao, D. Y.; Geibel, M. A. L.; Ritter, T. J. Am. Chem. Soc. 2010132, 14530–14536. 

9/ Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes 

Powers, D. C.; Benitez, D.; Tkatchouk, E.; Goddard, W. A., III; Ritter, T. J. Am. Chem. Soc. 2010, 132, 14092–14103.

8/ Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates 

Powers, D. C.; Geibel, M. A. L.; Klein, J. E. M. N.; Ritter, T. J. Am. Chem. Soc. 2009131, 17050–17051.

7/ Bimetallic Pd(III) Complexes in Palladium-Catalysed Carbon–Heteroatom Bond Formation

Powers, D. C.; Ritter, T.  Nature Chem. 20091, 302–309. (Highlighted in: Nature 2009459, 917–918.)

6/  Thermal Isomerizations of cis,anti,cis-Tricyclo[6.4.0.02,7]dodec-3-ene to trans- and cis-endo-Tricyclo[6.2.2.02,7]dodec-9-ene: Diradical Conformations and Stereochemical Outcomes in [1,3] Carbon Shifts 

Baldwin, J. E.; Bogdan, A. R.; Leber, P. A.; Powers, D. C. Tetrahedron 200763, 6331–6338.

5/ Thermal Chemistry of Bicyclo[4.2.0]oct-2-enes 

Powers, D. C.; Leber, P. A.; Gallagher, S. S.; Higgs, A. T.; McCullough, L. A.; Baldwin, J. E. J. Org. Chem. 200772, 187–194.

4/ Thermal Reactions of 7-d- and 8-d-Bicyclo[4.2.0]oct-2-enes  

Baldwin, J. E.; Leber, P. A.; Powers, D. C. J. Am. Chem. Soc. 2006128, 10020–10021.

3/ Thermal Reactions of 8-Methylbicyclo[4.2.0]oct-2-enes: Competitive Diradical-Mediated [1,3] Sigmatropic, Stereomutation, and Fragmentation Processes 

Bogle, X. S.; Leber, P. A.; McCullough, L. A.; Powers, D. C. J. Org. Chem200570, 8913–8918.

2/ Thermal Isomerization of cis,anti,cis-Tricyclo[6.3.0.02,7]undec-3-ene to endo-Tricyclo[5.2.2.02,6]undec-8-ene 

Baldwin, J. E.; Bogdan, A. R.; Leber, P. A.; Powers, D. C. Org. Lett. 20057, 5195–5197.

1/ Analysis of Natural Buffer Systems and the Impact of Acid Rain. An Environmental Project for First-Year Chemistry Students 

Powers, D. C.; Higgs, A. T.; Obley, M. L.; Leber, P. A.; Hess, K. R.; Yoder, C. H.  J. Chem. Educ. 200582, 274–277.